Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 64, Issue 20, Pages 3521-3530Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2011.623778
Keywords
Metal-organic framework; Nanomaterials; Zinc(II) oxide
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Funding
- Tarbiat Modares University
- National Iranian Gas Company
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The host and the apohost framework of [Zn-2(1,4-bdc)(2)(dabco)] center dot 4DMF center dot 1/2H(2)O (1 center dot 4DMF center dot 1/2H(2)O) (1,4-bdc = 1,4-benzenedicarboxylate and dabco = 1,4-diazabicyclo[2.2.2]octane) were used for the preparation of ZnO nanomaterials. With calcination of the host framework of 1 center dot 4DMF center dot 1/2H(2)O, ZnO nanoparticles could be fabricated. By the same process on fully desolvated framework of 1, ZnO microrods composed of ZnO nanoparticles were formed. These results indicate with removal of the guest solvent from the pores of this metal-organic framework (MOF), nanoparticle agglomeration increases and the role of this MOF in preparation of ZnO nanoparticles was reduced.
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