Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 63, Issue 2, Pages 296-306Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970903373922
Keywords
Chalcone thiosemicarbazone; Ruthenium(III) complexes; Spectroscopic studies; Carbon-carbon coupling reactions
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Funding
- Council of Scientific and Industrial Research (CSIR), New Delhi [01(2065)/06/EMR-II]
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New six-coordinate ruthenium(III) complexes [RuX(EPh3)(2)(L)] (X = Cl or Br; E = P or As; L = chalcone thiosemicarbazone) have been prepared by reacting [RuX3(EPh3)(3)] (X = Cl or Br; E = P or As) with chalcone thiosemicarbazones in benzene under reflux. The new complexes have been characterized by analytical and spectroscopic (IR, electronic, mass, and EPR) data. The redox behavior of the complexes has also been studied. Based on the above data, an octahedral structure has been assigned for all the complexes. The new complexes exhibit catalytic activity for carbon-carbon coupling reactions.
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