Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 62, Issue 13, Pages 2164-2171Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970902801493
Keywords
Schiff base; copper(ii) complex; synthesis; crystal structure; urease inhibitory property
Categories
Funding
- Natural Science Foundation of China [30771696]
- Natural Science Foundation of Zhejiang Province [Y407318]
- Science and Technology Plan of Huzhou [2007YS18]
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Two new copper(II) complexes, [CuL1(N3)] (1) and [CuL2(NCS)] (2) (HL1 = 4-chloro-2-[(2-piperidin-1-ylethylimino)methyl]phenol, HL2 = 4-chloro-2-[(2-morpholin-4-ylethylimino)methyl]phenol), were prepared and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. Complex 1 is an azide coordinated mononuclear complex, while complex 2 is a terminal thiocyanate coordinated mononuclear complex. The coppers in both complexes are four-coordinate, square-planar. Both complexes show potent urease inhibitory properties.
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