Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 62, Issue 17, Pages 2755-2763Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970902930375
Keywords
Lanthanide coordination polymer; Supramolecular network; Hydrothermal reaction; Photoluminescence property
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We have synthesized four coordination polymers with two different nitrogen containing organic ligands and different lanthanide metal ions, under hydrothermal condition. [{Ln2(bpdc)3(H2O)2}]n (Ln = Dy (1), Sm (2)) (bpdc = 2,2-bipyridine-3,3-dicarboxylic acid) are isostructural, with 2-D supramolecular layer structure composed from 1-D chains. Like 1 and 2, [{Ln(pzda)2(H2O)2} center dot 4H2O]n (Ln = Dy (3), Nd (4)) (pzda = pyrazine-2,6-dicarboxylic acid) are also isostructural with 1-D chain-like structures. The photoluminescence of 2 is studied.
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