4.3 Article

Syntheses and crystal structure studies of two compounds of quinolones

Journal

JOURNAL OF COORDINATION CHEMISTRY
Volume 62, Issue 14, Pages 2261-2267

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970902807268

Keywords

Crystal structure; enoxacin; zwitterion; ciprofloxacin

Funding

  1. Scientific Research Fund of Hunan Provincial Education Department [08c340]
  2. Foundation of Hunan University of Science and Technology [E55106]

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Two complexes with enoxacin and ciprofloxacin were synthesized and the crystal structures are reported. Compound 1, [Cu(H-Eno) Cl2] 3H2O (H-Eno = Enoxacin), crystallizes in the triclinic system, space group P 1, with lattice parameters a = 8.7731(12) , b = 9.4976(14) , c = 13.2033(19) , = 86.319(7), = 71.912(7), = 80.604(7), V = 1031.6(3) 3, Z = 2, Dc = 1.625 mgm-3. 2, [Mn(Cip)2] 2H2O (Cip = mono-anion of ciprofloxacin), crystallizes in the monoclinic, space group P2(1)/c, with lattice parameters a = 5.85690(10), b = 21.9490(6), c = 13.4443(3) , = 100.9700(10), V = 1696.72(7) 3, Z = 2, Dc = 1.459 mgm-3.

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