4.4 Article

Poly(lactic acid) nanocomposites with improved impact and thermal properties

Journal

JOURNAL OF COMPOSITE MATERIALS
Volume 48, Issue 2, Pages 155-163

Publisher

SAGE PUBLICATIONS LTD
DOI: 10.1177/0021998312469891

Keywords

Nanocomposites; poly(lactic acid); organoclay; functionalised rubber; properties

Funding

  1. Universiti Sains Malaysia [814070]
  2. USM [8021013, USM-RU-PGRS 8033002]

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PLA nanocomposites containing 2wt% of OMMT clay were prepared using twin screw extruder followed by injection moulding. EPR-g-MAH (5-20phr) was used to improve the impact properties of PLA/OMMT nanocomposites. The mechanical properties of PLA nanocomposites were studied through tensile, flexural and impact tests. The morphology and dispersion of OMMT were examined using TEM and XRD. The thermal properties were characterised using differential scanning calorimetry and thermogravimetric analysis. The impact strength and thermal stability of the PLA/OMMT nanocomposites were improved significantly in the presence of EPR-g-MAH. The degree of crystallinity of PLA/OMMT was influenced by the loading of EPR-g-MAH. TEM and XRD results revealed the formation of PLA nanocomposites as the OMMT was exfoliated in the presence of EPR-g-MAH.

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