4.7 Article

Novel sodium intercalated (NH4)2V6O16 platelets: High performance cathode materials for lithium-ion battery

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 415, Issue -, Pages 85-88

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2013.10.025

Keywords

Vanadium bronze; Intercalation; Cathode; Sodium-ion battery; Raman; Bi-cation; Hydrothermal; Oxalic acid; Sodium nitrate; Ammonium metavanadate

Funding

  1. National Science Foundation of China [51204058]
  2. Key Lab Adv Energy Mat Chem (Nankai University) [KLAEMC-OP201201]
  3. [2010J05025]
  4. [JA12037]

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A simple and versatile method for preparation of novel sodium intercalated (NH4)(2)V6O16 is developed via a simple hydrothermal route. It is found that ammonium sodium vanadium bronze displays higher discharge capacity and better rate cyclic stability than ammonium vanadium bronze as lithium-ion battery cathode material because of smaller charge transfer resistance, which would favor superior discharge capacity and rate performance. Crown Copyright (C) 2013 Published by Elsevier Inc. All rights reserved.

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