Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 391, Issue -, Pages 103-110Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2012.09.073
Keywords
Zwitterionic surface active ionic liquids; Aggregation behavior; Surface tension; Isothermal titration calorimetry; Fluorescence
Categories
Funding
- Natural Scientific Foundation of Shandong Province of China [ZR2011BM017, Z2007B3]
- Scientific and Technological Projects of Shandong Province of China [2009GG10003027]
- Independent Innovation Foundation of Shandong University (IIFSDU) of China [2009TS018]
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A novel class of zwitterionic surface active ionic liquids (SAILs), N-alkyl-N'-carboxymethyl imidazolium inner salts ([N-C-n, N'-CO2-Im], n = 10, 12, 14), was synthesized. Their aggregation behavior in aqueous solution was investigated by surface tension, isothermal titration calorimetry, and steady-state fluorescence. Compared with the reported imidazolium-based cationic SAILs, 1-alkyl-3-methylimidazolium bromide ([C(n)mim]Br) and zwitterionic betaine surfactants, (CnH2n+1N(CH3)(2)CH2COO-), [N-C-n, N'-CO2-Im] exhibits significantly lower critical micelle concentration (cmc) and surface tension at cmc (gamma(cmc)) values. It is attributed to the incorporation of a deprotonated carboxylic group into the head group, which weakens the electrostatic repulsion between head groups and favors micellization. The micellar aggregation number of [N-C-n, N'-CO2-Im] is larger than that of [C(n)mim]Br, while less than that of CnH2n+1N(CH3)(2)CH2COO-. Similar to the traditional zwitterionic surfactants, the surface activity and adsorption properties of [N-C-12, N'-CO2-Im] at air/water interface have a slight variation with temperature, pH, and ionic strength. This indicates that the present zwitterionic SAILs display the aggregation behavior much similar to zwitterionic surfactants, distinctly different from imidazolium-based cationic SAILs. Sets in low sensitivity to the environmental conditions, superior surface activity and unique physicochemical properties of ionic liquids, [N-C-n, N'-CO2-Im] can be exploited for utilizing as a potential substitute for conventional surfactants in certain fields. (C) 2012 Elsevier Inc. All rights reserved.
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