Concomitant synthesis of highly crystalline Zn-Al layered double hydroxide and ZnO: Phase interconversion and enhanced photocatalytic activity

Metal oxide/hydroxide with hierarchical nanostructures has emerged as one of the most promising materials for their unique, attractive properties and feasibility of applications in various fields. In this report, a concomitant synthesis of crystalline zinc aluminum layered double hydroxide (ZnAl-LDH) nanostructure and ZnO is presented using Al substrate as template. Studies on interconversion of ZnO to LDH phase in bulk solution under hydrothermal conditions produced Al-doped ZnO (AZO) in one case, and in other, it improves the crystallinity of LDH film templated on Al substrate. In presence of Al salt, the self-limiting growth nature of plate LDH turned to non-self-limiting. Materials obtained during phase transition, AZO in bulk solution and crystalline porous ZnAl-LDH on substrate, have been demonstrated as effective photocatalysts for decomposition of congo red in aqueous medium. (C) 2011 Elsevier Inc. All rights reserved.