4.7 Article

Silica nanoparticles for template synthesis of supported Pt and Pt-Ru electrocatalysts

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 351, Issue 2, Pages 365-373

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2010.07.068

Keywords

Platinum; Ruthenium; Template synthesis; Silica nanoparticle; Electrocatalyst; Methanol oxidation

Funding

  1. Department of Energy Office of Science [DE-FG02-06ER46292]
  2. National Science Foundation [CHE-0616878]
  3. ND-EPSCoR [UND0012419]
  4. EPSCoR
  5. Office Of The Director [0814442] Funding Source: National Science Foundation

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A simple method was developed for the template synthesis of silica-supported Pt and bimetallic Pt-Ru nanocatalysts. The synthesis used amine-functionalized silica nanoparticles as both template and support for the formation of metal nanoclusters with a precise composition, narrow size distribution, uniform shape and close spatial association. The nanocatalysts were compared with a commercial Pt-C catalyst used in fuel cell applications. Electrochemical measurements of methanol oxidation demonstrated higher catalytic activity for silica-supported Pt nanocatalysts and a reduced CO poisoning effect from co-templating of Pt and Ru. (C) 2010 Elsevier Inc. All rights reserved.

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