Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 328, Issue 2, Pages 367-373Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2008.08.067
Keywords
Mesoporous; Crystalline; Carbon; Titania; Composite; Hemoglobin; Immobilization; Bioelectrochemical properties
Categories
Funding
- NSF of China [20873086]
- Shanghai Science & Technology and Education Committee [07QH14011, 07SG49, 0652nm024, 08JC1417100, 07dZ22303]
- New Century Excellent Talents in Universities [NCET-07-0560]
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A direct-triblock-copolymer templating method is demonstrated to synthesize ordered mesoporous crystalline C-TiO2 (MCT) composites using phenolic resins and acid-base pairs [acidic TiCl4 and basic counterpart Ti(OC4H7)(4)] as carbon and titanium sources, respectively. The composites possess highly crystalline anatase pore walls that are glued by amorphous carbon, ordered mesostructure, high surface areas (similar to 200 m(2)/g), and large pore volumes (similar to 0.15 cm(3)/g). The titania content is as high as 87 wt%. MCT composite favors the immobilization of proteins and enhances the electrocatalytic properties in relation to the reduction of hydrogen peroxide. (C) 2008 Elsevier Inc. All rights reserved.
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