Journal
NEW JOURNAL OF CHEMISTRY
Volume 39, Issue 8, Pages 6445-6452Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj00655d
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Funding
- Shiraz University Research Council
- Iran National Elite Foundation
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This study describes our findings on a novel and cheap NiCl2 catalytic system under ligand-free conditions for the efficient thiocarbonylation, alkoxycarbonylation and amidocarbonylation reactions of aryl iodides in the presence of Cr(CO)(6) as the solid source of carbon monoxide under air. A variety of aryl iodides tolerated the reaction conditions and structurally different thiols, alcohols and amines were used efficiently. The corresponding thioesters, esters and amides were obtained in good to excellent yield at atmospheric pressure under mild reaction conditions.
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