Journal
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES
Volume 878, Issue 17-18, Pages 1264-1276Publisher
ELSEVIER
DOI: 10.1016/j.jchromb.2009.10.031
Keywords
Enantiomeric separation; Organophosphorus pesticides; High-performance liquid chromatography; Gas chromatography; Capillary electrophoresis; Toxicity; Environmental fate
Funding
- National Natural Science Foundations of China [20837002, 30771255]
- Natural Science Foundation of Zhejiang Province, China [Z506070]
- National Basic Research Program of China [2009CB421603]
- Program for Changjiang Scholars, Innovative Research Teams in Chinese Universities [IRT 0653]
- Special Funding Project for Public industry research of Ocean [JG0721]
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In recent years, the continuous evolution of the field of stereochemistry has produced a heightened awareness of the applications of pure enantiomers of agrochemicals. This review describes reports of the enantiomeric separation of commercial organophosphorus pesticides (OPs) and the applications of these methods to research on the enantioselectivity of the toxicity and environmental fate of these compounds. Chiral OPs can be analysed by high-performance liquid chromatography (HPLC), gas chromatography (GC), and capillary electrophoresis (CE). These different separation techniques for OP enantiomers are briefly discussed, and their applications are presented. (C) 2009 Elsevier By. All rights reserved.
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