Journal
JOURNAL OF CHROMATOGRAPHY A
Volume 1218, Issue 38, Pages 6561-6582Publisher
ELSEVIER
DOI: 10.1016/j.chroma.2011.07.084
Keywords
Fungicides; Chiral separation; Capillary electrophoresis; Gas chromatography; High performance liquid chromatography; Supercritical fluid chromatography
Funding
- Ministry of Science and Innovation [CTQ2009-09022/BQU]
- Comunidad Autonoma of Madrid (Spain)
- FEDER programme [S2009/AGR-1464 (ANALISYC-II)]
- Gobierno Vasco
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Fungicides are very important and diverse environmental and agricultural concern species. Their determination in commercial formulations or environmental matrices, requires highly efficient, selective and sensitive methods. A significant number of these chemicals are chiral with the activity residing usually in one of the enantiomers. The different toxicological and degradation behavior observed in many cases for fungicide enantiomers, results in the need to investigate them separately. For this purpose, separation techniques such as GC, HPLC, supercritical fluid chromatography (SFC) and CE have widely been employed although, at present, HPLC still dominates chromatographic chiral analysis of fungicides. This review covers the literature concerning the enantiomeric separation of fungicides usually employed in agriculture grouping the chiral separation methodologies developed for their analysis in environmental. biological, and food samples. (C) 2011 Elsevier B.V. All rights reserved.
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