Journal
JOURNAL OF CHROMATOGRAPHIC SCIENCE
Volume 51, Issue 7, Pages 608-618Publisher
OXFORD UNIV PRESS INC
DOI: 10.1093/chromsci/bmt024
Keywords
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Funding
- Specialized Research Fund for the Doctoral Program of Higher Education, Ministry of Education, China [20093227110010]
- Science Fund of Jiangsu University [08JDG001]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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The molecular imprinting technique is a highly predeterminative recognition technology. Molecularly imprinted polymers (MIPs) can be applied to the cleanup and preconcentration of analytes as the selective adsorbent of solid-phase extraction (SPE). In recent years, a new type of SPE has formed, molecularly imprinted polymer solid-phase extraction (MISPE), and has been widely applied to the extraction of agrochemicals. In this review, the mechanism of the molecular imprinting technique and the methodology of MIP preparations are explained. The extraction modes of MISPE, including offline and online, are discussed, and the applications of MISPE in the analysis of agrochemicals such as herbicides, fungicides and insecticides are summarized. It is concluded that MISPE is a powerful tool to selectively isolate agrochemicals from real samples with higher extraction and cleanup efficiency than commercial SPE and that it has great potential for broad applications.
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