Phase behavior of binary mixtures composed of ethylene carbonate and various organic solvents

Phase behaviors of the binary mixtures composed of ethylene carbonate (EC) and aliphatic alcohols to phenyl alcohols and alkylbenzenes were Investigated In addition heat of solution of EC into these organic solvents was measured The EC/methanol and EC/ethanol systems gave homogeneous solution at the temperature above their liquidus lines while the mixtures of EC and alcohols with longer alkyl chain showed a miscibility gap in a liquid phase and provided the monotectic-type phase diagram The liquid-liquid phase separation region expanded with the Increase in the alkyl chain length A similar phase behavior was also observed for the mixtures of EC and alkylbenzenes On the other hand the EC mixtures with omega-phenyl alcohols showed no miscibility gap in a liquid phase at least up to 4 phenylbutan-1-ol which has C4 alkyl chain intervening between phenyl and hydroxyl groups This result demonstrates that both of the hydroxyl and phenyl groups act to facilitate the mixing of aliphatic compounds with EC The phase behavior of these EC mixtures was analyzed applying the modified regular solution model in which the pair interaction energy was regarded as free energy The model calculation with the use of heat of solution of EC at infinite dilution as the pair interaction enthalpy reproduced well both of the experimentally obtained liquidus line and mutual solubility curve as well as monotectic point (C) 2010 Elsevier Ltd All rights reserved