Journal
JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 42, Issue 2, Pages 198-207Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2009.08.003
Keywords
Density; Partial molar volume; Aqueous amino acids; Glycine; L-Alanine; High temperature; High pressure; HKF equation; SOCW equation
Categories
Funding
- Ministry of Education, Youth and Sports of the Czech Republic [MSM6046137307]
- Research Centre Advanced Remediation Technologies and Processes at the TU Liberec
Ask authors/readers for more resources
Density data for dilute aqueous solutions of two amino acids (glycine, L-alanine) obtained using a flow vibrating-tube densimeter are presented together with partial molar volumes at infinite dilution (standard molar volumes, V-m,V-2 degrees) calculated from the measured data. The experiments were performed at temperatures from (298 up to 443) K at pressures close to the saturation line of water, at pressures in the range from (15 to 17) MPa, and at 30 MPa. Values of an analogue of isothermal compressibility, kappa(T,2)degrees = -(1/V-m,V-2 degrees)(partial derivative V-m,V-2 degrees/partial derivative p)(T), are also evaluated. Maxima on the curves V-m,V-2 degrees(T) and kappa(T,2)degrees T) are observed and discussed. The new data along with literature values of standard molar volumes and heat capacities are used for generating the recommended parameterization of an equation of state for standard molar thermodynamic properties of the aqueous amino acids. (C) 2009 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available