Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 140, Issue 16, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4873160
Keywords
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Funding
- Air Force Office of Scientific Research (AFOSR) [FA9550-11-1-0068, 10029173-S3]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1351968] Funding Source: National Science Foundation
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We report a joint photoelectron spectroscopic and theoretical study of the PtAl- and PtAl2- anions. The ground state structures and electronic configurations of these species were identified to be C-infinity v, (1)Sigma(+) for PtAl-, and C-2v, B-2(1) for PtAl2-. Structured anion photoelectron spectra of these clusters were recorded and interpreted using ab initio calculations. Good agreement between theory and experiment was found. All experimental features were successfully assigned to one-electron transitions from the ground state of the anions to the ground or excited states of the corresponding neutral species. (C) 2014 AIP Publishing LLC.
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