Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 140, Issue 16, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4871742
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Funding
- EPSRC on the UK national supercomputing facility Archer [EP/K013750/1]
- EPSRC [EP/K013750/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K013750/1] Funding Source: researchfish
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We have investigated the spectra of shock-frozen H2O2-H2O mixtures across the full composition range 99.1%-0.0% H2O2. In contrast to literature reports, we find that intermediate compositions (30%-70% H2O2) freeze to a solid solution rather than phase separating, which only occurs on annealing to just below the melting point. We have fully characterised the dihydrate H2O2 center dot 2H(2)O (48.6% H2O2) for the first time and shown that its spectrum can account for the features previously observed on the surface of a Au/TiO2 catalyst. (C) 2014 AIP Publishing LLC.
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