Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 140, Issue 11, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4867970
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Funding
- Engineering and Physical Sciences Research Council (U.K.) EPSRC(GB) [EP/E046150/1]
- Engineering and Physical Sciences Research Council [EP/J003921/1, EP/E046150/1] Funding Source: researchfish
- EPSRC [EP/J003921/1, EP/E046150/1] Funding Source: UKRI
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We report (nanosecond) resonance-enhanced multiphoton ionization (REMPI), (nanosecond) zero-kinetic-energy (ZEKE) and (picosecond) time-resolved slow-electron velocity map imaging (trSEVI) spectra of fully hydrogenated toluene (Tol-h(8)) and the deuterated-methyl group isotopologue (alpha(3)- Tol- d(3)). Vibrational assignments are made making use of the activity observed in the ZEKE and tr-SEVI spectra, together with the results from quantum chemical and previous experimental results. Here, we examine the 700-1500 cm (1) region of the REMPI spectrum, extending our previous work on the region less than or similar to 700 cm(-1). We provide assignments for the majority of the S-1 and cation bands observed, and in particular we gain insight regarding a number of regions where vibrations are coupled via Fermi resonance. We also gain insight into intramolecular vibrational redistribution in this molecule. (c) 2014 AIP Publishing LLC.
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