Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 141, Issue 18, Pages -Publisher
AIP Publishing
DOI: 10.1063/1.4900740
Keywords
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Funding
- Japan Society for the Promotion of Science (JSPS) KAKENHI Grant [19205002]
- Grants-in-Aid for Scientific Research [25410004] Funding Source: KAKEN
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Two silicon-bearing carbon chain radicals, SiC2N and SiC3N, were detected in the laboratory by Fourier transform microwave spectroscopy. Molecular constants including the hyperfine coupling constants have been determined for the two radicals in the ground electronic states. The SiC2N and SiC3N radicals have linear structures in the (2)Pi ground electronic states with inverted and regular fine structures, respectively, as are the cases for their isoelectronic radicals, SiC3H and SiC4H, indicating that the SiCnN radicals have similar electronic structures to the SiCn+1H radicals. The electronic structures of SiC2N and SiC3N in the ground states are discussed on the basis of the experimentally determined molecular constants. (C) 2014 AIP Publishing LLC.
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