Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 139, Issue 18, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4829766
Keywords
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Funding
- National Science Foundation [PHY-0969322]
- Linac Coherent Light Source at SLAC National Accelerator Laboratory, Office of Basic Energy Sciences, U.S. Department of Energy
- AMOS program within the Chemical Sciences, Geosciences, and Biosciences Division of the Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy [DE-AC02-76SF00515]
- Division Of Physics
- Direct For Mathematical & Physical Scien [0969322] Funding Source: National Science Foundation
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Nonradiative energy dissipation in electronically excited polyatomic molecules proceeds through conical intersections, loci of degeneracy between electronic states. We observe a marked enhancement of laser-induced double ionization in the vicinity of a conical intersection during a non-radiative transition. We measured double ionization by detecting the kinetic energy of ions released by laser-induced strong-field fragmentation during the ring-opening transition between 1,3-cyclohexadiene and 1,3,5-hexatriene. The enhancement of the double ionization correlates with the conical intersection between the HOMO and LUMO orbitals. (C) 2013 AIP Publishing LLC.
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