Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 136, Issue 14, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3702644
Keywords
-
Funding
- Deutsche Forschungsgemeinschaft [RE 1469/7-1]
- Impuls-und Vernetzungsfonds of the Helmholtz-Association [VH-NG-423]
- Department of Energy, Basic Energy Sciences [DE-AC02-05CH11231]
Ask authors/readers for more resources
The electronic structure of gas-phase H2O and D2O molecules has been investigated using resonant inelastic soft x-ray scattering (RIXS). We observe spectator shifts for all valence orbitals when exciting into the lowest three absorption resonances. Strong changes of the relative valence orbital emission intensities are found when exciting into the different absorption resonances, which can be related to the angular anisotropy of the RIXS process. Furthermore, excitation into the 4a(1) resonance leads to nuclear dynamics on the time scale of the RIXS process; we find evidence for vibrational coupling and molecular dissociation in both, the spectator and the participant emission. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3702644]
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available