Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 137, Issue 4, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4734310
Keywords
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Funding
- Deutsche Forschungsgemeinschaft [Pu 180/6-1]
- Research Council for Natural Sciences of the Academy of Finland
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High-resolution normal Auger-electron spectra of carbonyl sulfide subsequent to S 2p(-1) photoionization at photon energies of 200, 220, and 240 eV are reported along with corresponding photoelectron spectra. In addition, theoretical results are presented that take the core-hole orientation of the various spin-orbit-split and molecular-field-split S 2p(-1) states into account. Auger transitions to eight metastable dicationic final states are observed and assigned on the basis of the theoretical results. From Franck-Condon analysis, assuming Morse potentials along the normal coordinates for seven of the observed quasi-stable dicationic final states, information on the potential-energy surfaces is derived and compared with theoretical results from the literature. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4734310]
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