Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 136, Issue 13, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3701615
Keywords
-
Funding
- NWO
- NWO-VICI
Ask authors/readers for more resources
Self-assembly and alignment of anisotropic colloidal particles are important processes that can be influenced by external electric fields. However, dielectric nanoparticles are generally hard to align this way because of their small size and low polarizability. In this work, we employ the coupled dipole method to show that the minimum size parameter for which a particle may be aligned using an external electric field depends on the dimension ratio that defines the exact shape of the particle. We show, for rods, platelets, bowls, and dumbbells, that the optimal dimension ratio (the dimension ratio for which the size parameter that first allows alignment is minimal) depends on a nontrivial competition between particle bulkiness and anisotropy because more bulkiness implies more polarizable substance and thus higher polarizability, while more anisotropy implies a larger (relative) difference in polarizability. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3701615]
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available