4.7 Article

Theory and simulations of quantum glass forming liquids

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 136, Issue 7, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3684881

Keywords

integration; molecular dynamics method; quantum fluids; vitrification

Funding

  1. Kakenhi [21015001, 2154016]
  2. NSF [CHE-0910943, CHE-0719089]
  3. US-Israel Binational Science Foundation
  4. Direct For Mathematical & Physical Scien
  5. Division Of Chemistry [0910943] Funding Source: National Science Foundation
  6. Grants-in-Aid for Scientific Research [21015001, 21540416] Funding Source: KAKEN

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A comprehensive microscopic dynamical theory is presented for the description of quantum fluids as they transform into glasses. The theory is based on a quantum extension of mode-coupling theory. Novel effects are predicted, such as reentrant behavior of dynamical relaxation times. These predictions are supported by path integral ring polymer molecular dynamics simulations. The simulations provide detailed insight into the factors that govern slow dynamics in glassy quantum fluids. Connection to other recent work on both quantum glasses as well as quantum optimization problems is presented. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3684881]

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