Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 134, Issue 14, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3578609
Keywords
-
Funding
- South African National Laser Centre (NLC)
- National Research Foundation (NRF)
Ask authors/readers for more resources
Measurements of the temperature dependence of the Buckingham effect (electric-field-gradient-induced birefringence, EFGIB) for gaseous nitrous oxide are presented. Measurements span the temperature range 298.5-473.9 K, which allows for separation of the temperature-independent hyperpolarizability term from the temperature-dependent quadrupole term, yielding a quadrupole moment of Theta = (-11.03 +/- 0.41) x 10(-40) C m(2), and a hyperpolarizability term of b = (-0.638 +/- 0.063) x 10(-60) C-3 m(4) J(-2). For dipolar molecules, the quadrupole moment is origin dependent, and the value reported here is referred to an origin called the effective quadrupole center (EQC). Comparison of this value with the center of mass (CM) quadrupole moment obtained from MBER experiments yields information about the dynamic dipole-quadrupole and dipole-magnetic dipole polarizabilities. The temperature-independent term, previously assumed to contribute negligibly to the EFGIB, is found to contribute some (5.2 +/- 0.6)% to the effect at room temperature and clearly needs to be accounted for if the quadrupole moment is to be definitively established. (C) 2011 American Institute of Physics. [doi:10.1063/1.3578609]
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available