4.7 Article

Dynamically skewed lines: Rotations in superfluid helium

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 133, Issue 5, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3469816

Keywords

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Funding

  1. NSF Center for Chemical Innovation [CHE-0802913]

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Dynamically skewed spectral lines arise for chirped damped oscillators. We extend this to the chirped damped rotor and apply it to treat the rovibrational line shapes of small molecules isolated in superfluid helium. The simple analysis generates valuable physical insights on the prevailing dynamics of a rotor coupled to its environment. (C) 2010 American Institute of Physics. [doi:10.1063/1.3469816]

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