Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 130, Issue 8, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3080163
Keywords
excited states; fullerenes; hydrogen neutral molecules; infrared spectra; rotational states; spectral line intensity; translational states; vibrational states
Funding
- EPSRC [6138, 7011]
- University Research Fellowship (Royal Society)
- EPSRC [EP/G035695/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G035695/1] Funding Source: researchfish
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We report the observation of quantized translational and rotational motion of molecular hydrogen inside the cages of C-60. Narrow infrared absorption lines at the temperature of 6 K correspond to vibrational excitations in combination with translational and rotational excitations and show well-resolved splittings due to the coupling between translational and rotational modes of the endohedral H-2 molecule. A theoretical model shows that H-2 inside C-60 is a three-dimensional quantum rotor moving in a nearly spherical potential. The theory provides both the frequencies and the intensities of the observed infrared transitions. Good agreement with the experimental results is obtained by fitting a small number of empirical parameters to describe the confining potential, as well as the relative concentration of ortho- and para-H-2.
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