Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 131, Issue 15, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3250426
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Funding
- INTAS [05-1000008-8017]
- Division of Chemistry and Material Science of the Russian Academy of Sciences
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IR spectra of xenon hydrides (HXeCCH, HXeCC, and HXeH) obtained from different xenon isotopes ((129)Xe and (136)Xe) exhibit a small but detectable and reproducible isotopic shift in the absorptions assigned to H-Xe stretching (by 0.17-0.38 cm(-1)). To our knowledge, it is the first direct experimental evidence for the H-Xe bond in HXeY type compounds. The shift magnitude is in good agreement with quantum-chemical calculations. (C) 2009 American Institute of Physics. [doi: 10.1063/1.3250426]
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