Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 130, Issue 3, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3058730
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Funding
- CNRS institution
- AFOSR [FA9550-04-1-0057]
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We employ the velocity map imaging technique to measure kinetic energy and angular distributions of state selected CH3 (v(2)=0,1,2,3) and Br (P-2(3/2), P-2(1/2)) photofragments produced by methyl bromide photolysis at 215.9 nm. These results show unambiguously that the Br and Br* forming channels result in different vibrational excitations of the umbrella mode of the methyl fragment. Low energy structured features appear on the images, which arise from C(H)3Br(+) photodissociation near 330 nm. The excess energy of the probe laser photon is channeled into CH3+ vibrational excitation, most probably in the v(4) degenerate bend. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3058730]
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