Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 131, Issue 1, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3157185
Keywords
ab initio calculations; free radicals; ground states; laser cooling; molecule-photon collisions; multiphoton spectra; organic compounds; photoelectron spectra; photoexcitation; photoionisation; resonant states; rotational-vibrational states; Rydberg states; vibrational states
Funding
- ETH Zurich
- Swiss National Science Foundation [200020-116245, 200020-115974]
Ask authors/readers for more resources
Pulsed-field-ionization zero-kinetic-energy photoelectron spectra of jet-cooled allyl radical (C3H5) have been recorded following single-photon and resonant multiphoton excitation. Simulations based on an orbital ionization model and rovibronic photoionization selection rules reliably describe the observed intensity distributions in the photoelectron spectra obtained from single-photon excitation from the ground state and resonant multiphoton excitation via the 3s and the 3p Rydberg states. More than 30 transitions to vibrational levels of the cation were identified and assigned on the basis of predictions from ab initio calculations.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available