Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 130, Issue 4, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3062840
Keywords
adsorbed layers; biochemistry; electrodes; electrolytes; gold; molecular biophysics; monolayers; organic compounds
Funding
- UK EPSRC
- EU through a Marie Curie Fellowship
- UK North West Development Agency
- North West Science Fund
- Engineering and Physical Sciences Research Council [EP/C510208/1] Funding Source: researchfish
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Reflection anisotropy spectroscopy (RAS) has been used to show that at saturation coverage adenine adsorbs on the Au(110)/electrolyte interface in a base-stacking configuration with the plane of the bases orientated vertically on the surface and with the long axis of the molecules parallel to the [110] direction. Changes in the RAS observed from adsorbed adenine as a result of changes in the potential applied to the Au(110) electrode could arise from slight changes in the orientation of the molecules in the vertical plane.
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