Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 128, Issue 19, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2919050
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Funding
- NIGMS NIH HHS [R01 GM059230, GM59230] Funding Source: Medline
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Two-dimensional infrared photon echo and pump probe studies of the OH stretch vibration provide a sensitive probe of the correlations and couplings in the hydrogen bond network of liquid water. The nonlinear response is simulated using numerical integration of the Schrodinger equation with a Hamiltonian constructed to explicitly treat intermolecular coupling and nonadiabatic effects in the highly disordered singly and doubly excited vibrational exciton manifolds. The simulated two-dimensional spectra are in close agreement with our recent experimental results. The high sensitivity of the OH stretch vibration to the bath dynamics is found to arise from intramolecular mixing between states in the two-dimensional anharmonic OH stretch potential. Surprisingly small intermolecular couplings reproduce the experimentally observed intermolecular energy transfer times. (c) 2008 American Institute of Physics.
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