4.2 Article Proceedings Paper

Silica-Based Membranes with Molecular-Net-Sieving Properties: Development and Applications

Journal

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Volume 51, Issue 9, Pages 713-725

Publisher

SOC CHEMICAL ENG JAPAN
DOI: 10.1252/jcej.17we235

Keywords

Inorganic Membranes; Silica; Organosilica; Separation; Gas; Pervaporation; Reverse Osmosis

Funding

  1. Japan Society for the Promotion of Science (JSPS) KAKENHI [15H02313, 18H03855]
  2. Grants-in-Aid for Scientific Research [18H03855] Funding Source: KAKEN

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Over the past several decades, inorganic membranes composed of zeolite, silica, carbon, and metal/organic frameworks (MOF) have improved dramatically in terms of fabrication and application. Pure silica (SiO2) and organosilica membranes for use in molecular separation are the focus of this review. First, the fabrication of these silica-based membranes is outlined to highlight the great progress achieved in sol-gel and CVD processing. Then, applications in gas- and liquid-phase separations and an evaluation of pore sizes are summarized and future perspectives are discussed.

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