4.5 Article

A Simplified Poschl-Teller Potential: An Instructive Exercise for Introductory Quantum Mechanics

Journal

JOURNAL OF CHEMICAL EDUCATION
Volume 95, Issue 11, Pages 1989-1995

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jchemed.8b00029

Keywords

Upper-Division Undergraduate; Graduate Education/Research; Physical Chemistry; Quantum Chemistry

Funding

  1. Department of Chemistry and Biochemistry at Kettering University

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The quantum mechanics of a simplified Poschl-Teller potential in one dimension is analyzed at an elementary level. The number of bound states of this potential is determined by a parameter l characterizing the depth of the potential energy. The resulting collection of potentials with varying depth, as well as their ground state energies, is found by requiring the ground state wave function to be the hyperbolic secant function raised to power I. A step-by-step operator-based strategy for the construction of the eigenfunctions corresponding to all other bound states and their eigenenergies is discussed. We also show how all these results can be alternatively obtained by means of the Legendre differential equation, familiar from the rigid -rotor and hydrogen atom problems. The connection between all these problems is discussed while highlighting the use of this model for teaching introductory quantum mechanics.

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