4.5 Article

A Brief History of Fluorescence and Phosphorescence before the Emergence of Quantum Theory

Journal

JOURNAL OF CHEMICAL EDUCATION
Volume 88, Issue 6, Pages 731-738

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ed100182h

Keywords

General Public; Upper-Division Undergraduate; Analytical Chemistry; Physical Chemistry; History/Philosophy; Textbooks/Reference Books; Fluorescence Spectroscopy; Quantitative Analysis

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Fluorescence and phosphorescence are two forms of photoluminescence used in modern research and in practical applications. The early observations of these phenomena, before the emergence of quantum theory, highlight the investigation into the mechanism of light emission. In contrast to incandescence, photoluminescence does not require high temperatures and does not usually produce noticeable heat. Such a cold light was the object of an interesting controversy in the 19th century: does it fit into thermodynamics? The early applications, such as the fluorescent tube, fluorescence analysis, and fluorescent tracers, are described.

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