Journal
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Volume 44, Issue 3, Pages 151-160Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10870-014-0495-5
Keywords
Iridium; 8-Oxyquinolinate; 2-Methyl-8-oxyquinolinate; 7-Azaindolate; Triphenylsilyl; Triphenyltin; Crystal structure
Categories
Funding
- University of the Witwatersrand
- NRF
Ask authors/readers for more resources
The X-ray structures of the complexes [Ir(8OQ)(1,5-cod)] (1), [Ir(8OQd)(1,5-cod)] (2) and [Ir-2(mu-7AI)(2)(1,5-cod)(2)] (3) (where 8OQ, 8OQd and 7AI are anions derived from 8-hydroxyquinoline, 2-methyl-8-hydroxyquinoline (8-hydroxyquinaldine) and 7-azaindole, respectively) are mononuclear in the case of 1 and 2, with evidence of steric strain induced by the methyl group in 2 and dinuclear in the case of 3. The oxidative addition products [Ir(8OQd)(H)(EPh3)(1,5-cod)] [E = Si (4), Sn (5)], formed by the reaction of 2 with SiHPh3 and SnHPh3, respectively, show significant conformational differences in the solid state.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available