Journal
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Volume 39, Issue 4, Pages 241-245Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10870-008-9452-5
Keywords
Iridium complex; Iridium(III)bis(2-p-tolyl-benzothiazolato-N,C-2)(acetylacetonate); Crystal structure; Photophysical properties
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Funding
- National Natural Science Foundation of China [20702064]
- Natural Science Foundation of South-Central University for Nationalities [YZZ07007]
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A novel thiazole-based iridium (III) complex (iridium(III)bis(2-p-tolyl-benzothiazolato-N,C-2)(acetylacetonate)) has been prepared and fully characterized by EA, IR, H-1-NMR and MS. The molecular structure of the complex has been determined by single crystal X-ray diffraction analysis. The iridium (III) center adopts a distorted octahedral geometry with cis-O-O, cis-C-C, and trans-N-N chelate disposition. The complex crystallizes in the orthorhombic Pbca space group with cell parameters a = 10.1388(7) angstrom, b = 18.3565(12) angstrom, c = 31.021(2) angstrom, alpha = beta = gamma = 90 degrees and Z = 8. The electronic absorption and emission spectra of this complex have been investigated.
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