Journal
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Volume 39, Issue 4, Pages 229-240Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10870-008-9474-z
Keywords
Porphyrin; Coordination polymers; Structural motif; Topological control
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Funding
- University of Nebraska-Lincoln
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In this review, we classify 1D, 2D, and 3D structural motifs found in porphyrinic coordination polymers assembled from 5,10,15,20-tetrapyridylporphyrin (TPyP) and its derivatives. The classifications are based on dimensionality, metal-to-porphyrin linkage, porphyrin type, and metal-to-porphyrin ratio. 1D porphyrin polymers often share the same connectivity (or structural motifs) with analogous 2D and 3D polymers. We identify interrelationships among 1D, 2D, and 3D coordination polymers and examine the connectivity of such interrelated structures. We also discuss the broad similarities and differences of the synthetic methods of all structures presented here.
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