Journal
JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 59, Issue 2, Pages 176-182Publisher
AMER CHEMICAL SOC
DOI: 10.1021/je301276s
Keywords
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Funding
- Ph.D. Programs Foundation of the Ministry of Education of China [20110205110014]
- Fundamental Research Funds for the Central Universities [2013G2291015, 2013G1291071, 2013G1502038]
- National Training Projects of the University Students' Innovation and Entrepreneurship program [201310710057]
- Natural Science Foundation of ShaanXi Province [2013JQ2019]
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In this work, the phase diagrams and the liquid liquid equilibrium (LLE) data at 298.15 K of the aqueous [EPy]BF4 + ammonium sulfate + H2O, [EPy]BF4 + sodium dihydrogen phosphate + H2O, and [EPy]BF4 + sodium carbonate + H2O two-phase systems were experimentally determined. The Merchuk equation was used to correlate the binodal data of the investigated systems. The tie-line data were correlated according to the Othmer-Tobias and Bancroft equations, the Setschenow equation, and a two-parameter equation. The results indicate that all of these equations can be successfully used to correlate the experimental data of the investigated systems at 298.15 K. Both the calculated effective excluded volume (EEV) and the binodal curves, which were plotted using the mass fractions, indicate the phase-separation abilities of the investigated salts, which follow the following order: Na2CO3 > (NH4)(2)SO4 > NaH2PO4.
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