4.2 Article

Phase Equilibrium and Latent Heat of Tetra-n-butylammonium Chloride Semi-Clathrate Hydrate

Journal

JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 56, Issue 8, Pages 3416-3418

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/je2004116

Keywords

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Funding

  1. Higher College Doctoral Subject Foundation of China [20070558059]
  2. Science and Technology of Department of Housing and Urban-Rural Development of China [2010-K6-4]
  3. Suzhou Planning Project of Science and Technology of China [SYG201042]
  4. Suzhou University of Science and Technology Foundation [380910003, 330911207]

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Hydrate equilibrium conditions for tetra-n-butyl ammonium chloride (TBAC) aqueous solutions were experimentally studied and reported in the concentration range of (5 to 40) mass % and the temperature range of (275.45 to 288.05) K at atmospheric pressure. The phase change temperature of TBAC hydrate increased with the increase of the concentration of TBAC aqueous solution when the concentration of TBAC aqueous solution was less than 35 mass %. The latent heat of TBAC hydrate was about 169.2 kJ.kg(-1).

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