Journal
JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 54, Issue 5, Pages 1477-1482Publisher
AMER CHEMICAL SOC
DOI: 10.1021/je800787t
Keywords
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Funding
- National Natural Science Foundation of China [20603014, 20673059]
- Chinese Ministry of Education [105074]
- Committee of Science and Technology of Shanghai [0652nm010, 08JC1408100]
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The liquid-liquid coexistence of dimethyl carbonate + n-decane and dimethyl carbonate + n-tetradecane has been determined within 10 K from the critical temperature by measurements of refractive index n. The critical amplitude B and the critical exponent beta have been deduced from the coexistence curves. Experimental values of beta are consistent with theoretical prediction. The results have also been analyzed to determine Wegner-correction terms when beta and Delta are fixed at the theoretical values and to examine the asymmetric behavior of the diameters of the coexistence curves.
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