4.2 Article

Experimental measurements of vapor-liquid equilibria of the H2O+CO2+CH4 ternary system

Journal

JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 53, Issue 6, Pages 1246-1249

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/je700473e

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Reported are the experimental measurements on vapor-liquid equilibria in the H2O + CO2 + CH4 ternary system at temperatures from (324 to 375) K and pressures from (10 to 50) MPa. The results indicate that the CH4 solubility in the ternary mixture is about 10 % to 40 % more than that calculated by interpolation from the Henry's law constants of the binary system, H2O + CH4, and the solubility of CO2 is 6 % to 20 % more than what is calculated by the interpolation from the Henry's law constants of the binary mixture, H2O + CO2.

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