4.2 Article

Densities and excess enthalpies for ionic liquids plus ethanol or plus nitromethane

Journal

JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 53, Issue 6, Pages 1298-1301

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/je700754k

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Density in the temperature interval (293.15 to 323.15) K and excess enthalpy at 303.15 K are determined for 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4] + ethanol or + nitromethane and 1-butyl-3-methylimidazolium methylsulfate [BMIM][MeSO4] + ethanol or + nitromethane. Excess molar volumes are calculated at several temperatures from density data. Both excess properties are fitted to a Redlich-Kister-based equation, and results are discussed in terms of the chemical nature of the compounds that form the mixtures.

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