Synthesis, characterization and reactivity of high hydrothermally stable Cu-SAPO-34 materials prepared by one-pot processes

A Cu-SAPO-34 material with very high activity for selective catalytic reduction (SCR) of NOx and hydrothermal stability has been synthesized following a sequential rationalized design. By using specific combinations of organic structure directing agents (OSDAs) and gel compositions in a one-pot method, it was possible to control Cu occupancy, framework Si distribution, and to maximize the yield of solids. The amount of Cu2+ is maximized and remains stable even after steaming at 750 degrees C for 13 h. (C) 2014 Elsevier Inc. All rights reserved.