4.8 Article

Bifunctional iridium-(2-aminoterephthalate)-Zr-MOF chemoselective catalyst for the synthesis of secondary amines by one-pot three-step cascade reaction

Journal

JOURNAL OF CATALYSIS
Volume 299, Issue -, Pages 137-145

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2012.12.004

Keywords

MOF; Post-functionalization; One-pot; Domino; Reductive amination; Heterogenized catalyst

Funding

  1. CONSOLIDER-INGENIO [CSD-0050-MULTICAT]
  2. MINECO of Spain [MAT2011-29020-C02-02]

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A simple and efficient method for the synthesis of N-alkyl amines via a cascade reaction (hydrogenation + reductive amination) using a new recyclable hybrid catalyst that combines the catalytic power of transition metal complexes with the architecture of metal organic frameworks (MOFs). (C) 2012 Elsevier Inc. All rights reserved.

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