4.8 Article

Rasta resin as support for TBD in base-catalyzed organic processes

Journal

JOURNAL OF CATALYSIS
Volume 285, Issue 1, Pages 216-222

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2011.09.032

Keywords

Heterogeneous catalysis; Solvent-free conditions; 1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD); Polymer-supported organocatalysts

Funding

  1. Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR)
  2. Universita degli Studi di Perugia
  3. FONDAZIONE Cassa di Risparmio di Perugia [prot. 2008.031.0356]

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Although its intriguing features, such as uniform functionalization through the entire beads and a very high-loading capacity are suitable candidates for solid-phase synthesis and reagent-scavenging, the use of Rasta resin as support for organocatalysis has been little explored. In this contribution, Rasta polymer has been used to preparation of high-loading Rasta-TBD. This catalyst has been able to efficiently promote several organic transformations with constantly good and promising results. (C) 2011 Elsevier Inc. All rights reserved.

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