Journal
JOURNAL OF CATALYSIS
Volume 291, Issue -, Pages 87-94Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2012.04.008
Keywords
Zeolitic microcapsule; Multifunction catalyst; Isolation of active sites; Phenylethylamine; Dynamic kinetic resolution
Categories
Funding
- NSFC [21073041, 30828010, 20873025, 20890122]
- STCSM [10QH1400300, 08DZ2270500, 09DZ2271400]
- 973 Program
- 863 Program [2009CB930400, 2009CB623506, 2009AA033701]
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The platinum-encapsulated zeolitically microcapsular catalyst, associated with the immobilized Candida antartica lipase B (Novozyme (R) 435), is successfully employed in the dynamic kinetic resolution of phenylethylamine. A conversion of 80% and a selectivity of 95% are achieved, and negligible loss of activity is detected even after reaction of 5 runs. It is found that the existence of the silicalite-1 shell not only effectively prevents the deactivation of both enzyme and Pt by isolating them in different regions of reaction system, but also significantly reduces the formation of by-products on the Pt nanoparticles within the protected space of zeolitic microcapsule. Such features of zeolitic shell should further promote the designing of various catalysts for multistep reaction network. (C) 2012 Elsevier Inc. All rights reserved.
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