Journal
JOURNAL OF CATALYSIS
Volume 283, Issue 2, Pages 192-201Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2011.08.011
Keywords
Gold; Biosynthesis; Ionic liquid; TS-1; Catalyst; Propylene epoxidation; Immobilization; Special adsorption
Categories
Funding
- National Natural Science Foundation of China [21036004, 20776120, 20976146]
- Fundamental Research Funds for the Central Universities [2010121051]
- Research Fund for the Doctoral Program of Higher Education of China [20100121110032]
- Natural Science Foundation of Fujian Province of China [2010J05032, 2010J01052, 2008J0169]
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The direct vapor-phase epoxidation of propylene in the presence of hydrogen and oxygen was studied at a space velocity of 7000 mL h(-1) g(cat)(-1), over gold catalysts with varying gold and titanium contents prepared by ionic liquid-enhanced immobilization (ILEI) method in which biosynthesized gold nanoparticles (GNPs) were immobilized onto the titanium silicalite-1 (TS-1) supports through the assistance of a small amount of 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]). The results showed that [BMIM]. specially adsorbed onto the support to increase its isoelectric point, leading to the enhanced immobilization. The propylene conversion of 14.6% and PO formation rate of 164.4 g(po) K g(cat)(-1) h(-1) were higher than those in any other reports, probably attributing to enhanced interaction between the GNPs and TS-1. Furthermore, the excellent activity and high selectivity of the Au/TS-1 catalysts at a relatively high reaction temperature might be attributed to the existence of residual biomolecules on the catalysts. (C) 2011 Elsevier Inc. All rights reserved.
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